Optout/optin is only for the greylisting option.
White/blacklisting is for spam checking.
A mail is send to one of your domain's, then first the greylisting kicks in, what greylisting does is blocking the SENDER for a few minutes.
A normal and good configured mail server will retry the transmission after a few minutes, where spammers who use Viruses/maleware don't do this, thus you receive less spam but there can be a delay in the receiving of mail.
If the SENDERS mail address or IP is on the optout domain or email list they are never blocked in this first attempt (so no delay in mail receiving).
(note that the system automatically adds hosts/mailaddresses to the optout lists if they pass the second attempt.)
When the mail is received by E.F.A. after this then the mail is checked against the white/blacklist (in E.F.A. web interface under LISTS).
If the mail address or domain is whitelisted the mail is always marked as OK and not checked for spam content (and if on the blacklist it is always marked as SPAM)
As it are 2 seperate systems/lists it can be a bit confusing but thats just the way it works
