No problem, I think to myself. I've got a proper commercial wildcard SSL cert that covers this domain and I can use that. So I updated /etc/postfix/main.cf to point at the new certifcate (.crt file, not a pem), the new private key (.key) and the certificate chain file (.ca-bundle) and restarted postfix but on checking again with checkTLS, I now fail the test.
The certificate and key are working fine on a number of CentOS web servers and even a couple of webmin installs (just discovered whilst searching the forum that eFa installs webmin

Thanks for any pointers.
Matt